The dataset contains Gas Chromatography (GC) data pertaining to the bulk electrolytic experiments, biocatalytic, organocatalytic reactions, and standards used in the study. The standard GC files calibrate the sensitivity of the column in the Gas Chromatograph to 1-heptanol, heptanal, and the corresponding alpha-hydrazino aldehyde. This information is used to quantify the peaks of 1-heptanol and heptanal obtained in the bulk electrolytic experiments and the alpha-hydrazino aldehyde obtained in the organocatalytic step.